Bulk heterojunction morphology of polymer:fullerene blends revealed by ultrafast spectroscopy.

ABSTRACT: Morphology of organic photovoltaic bulk heterojunctions (BHJs) - a nanoscale texture of the donor and acceptor phases - is one of the key factors influencing efficiency of organic solar cells. Detailed knowledge of the morphology is hampered by the fact that it is notoriously difficult to investigate by microscopic methods. Here we all-optically track the exciton harvesting dynamics in the fullerene acceptor phase from which subdivision of the fullerene domain sizes into the mixed phase (2-15 nm) and large (>50 nm) domains is readily obtained via the Monte-Carlo simulations. These results were independently confirmed by a combination of X-ray scattering, electron and atomic-force microscopies, and time-resolved photoluminescence spectroscopy. In the large domains, the excitons are lost due

SUBMITTER: Serbenta A 

PROVIDER: S-EPMC5099942 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature