The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²-P₂)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers.

ABSTRACT: The three-component reaction of the tetrahedral diphosphorus complex [Cp₂Mo₂(CO)₄(η²-P₂)] (1), with Ag[BF₄] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two-component reactions with organic molecules in addition of metal ions.

SUBMITTER: Moussa ME 

PROVIDER: S-EPMC5101867 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature