Ontology highlight
ABSTRACT:
SUBMITTER: Tolnai GL
PROVIDER: S-EPMC5113792 | biostudies-literature | 2016 Sep
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20160816 37
Novel methodology for O-functionalization of carbohydrate derivatives has been established using bench-stable and easily prepared iodonium(III) reagents. Both electron-withdrawing and electron-donating aryl groups were introduced under ambient conditions and without precautions to exclude air or moisture. Furthermore, the approach was extended both to full arylation of cyclodextrin, and to trifluoroethylation of carbohydrate derivatives. This is the first general approach to introduce traditiona ...[more]