Type I Clathrates as Novel Silicon Anodes: An Electrochemical and Structural Investigation.

ABSTRACT: Silicon clathrates contain cage-like structures that can encapsulate various guest atoms or molecules. An electrochemical evaluation of type I silicon clathrates based on Ba₈Al _y Si_46-y as the anode material for lithium-ion batteries is presented here. Postcycling characterization with nuclear magnetic resonance and X-ray diffraction shows no discernible structural or volume changes even after electrochemical insertion of 44 Li (≈1 Li/Si) into the clathrate structure. The observed properties are in stark contrast with lithiation of other silicon anodes, which become amorphous and suffer from large volume changes. The electrochemical reactions are proposed to occur as single phase reactions at approximately 0.2 and 0.4 V versus Li/Li⁺

SUBMITTER: Li Y 

PROVIDER: S-EPMC5115401 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature