Tuning the Reactivity of Terminal Nickel(III)-Oxygen Adducts for C-H Bond Activation.

ABSTRACT: Two metastable Ni^III complexes, [Ni^III(OAc)(L)] and [Ni^III(ONO₂)(L)] (L = N,N'-(2,6-dimethylphenyl)-2,6-pyridinedicarboxamidate, OAc = acetate), were prepared, adding to the previously prepared [Ni^III(OCO₂H)(L)], with the purpose of probing the properties of terminal late-transition metal oxidants. These high-valent oxidants were prepared by the one-electron oxidation of their Ni^II precursors ([Ni^II(OAc)(L)]^- and [Ni^II(ONO₂)(L)]^-) with tris(4-bromophenyl)ammoniumyl hexachloroantimonate. Fascinatingly, the reaction between any [Ni^II(X)(L)]^- and NaOCl/acetic acid (AcOH) or cerium ammonium nitrate ((NH₄)₂[Ce^IV

SUBMITTER: Pirovano P 

PROVIDER: S-EPMC5119486 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature