Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms.

ABSTRACT: The air-stable mononuclear Co(ii) compounds [Co^II(Tpm)₂][ClO₄]₂ (1, Tpm = tris(pyrazol-1-yl)methane), [Co^II(Tpm)₂][BPh₄]₂·2MeCN (2) with trigonal antiprismatic geometry (trigonally elongated octahedral geometry) are reported. Magnetic and theoretical studies reveal that the complexes exhibit single-molecule magnet behavior with uniaxial anisotropy and a huge energy difference between ground and first excited Karmers' doublets (∼200 cm^-1). Under applied DC fields, compounds 1 and 2 exhibit frequency and temperature dependence of the imaginary susceptibility. The fit of the data to an Orbach relaxation process yields effective energy barriers of 30.6(1) and 44.7(6) c

SUBMITTER: Zhang YZ 

PROVIDER: S-EPMC5125373 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature