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Hydroacenes Made Easy by Gold(I) Catalysis.


ABSTRACT: A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au(I) -catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene.

SUBMITTER: Dorel R 

PROVIDER: S-EPMC5132091 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature

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Hydroacenes Made Easy by Gold(I) Catalysis.

Dorel Ruth R   McGonigal Paul R PR   Echavarren Antonio M AM  

Angewandte Chemie (International ed. in English) 20160706 37


A novel strategy for the synthesis of partially saturated acene derivatives has been developed based on a Au(I) -catalyzed cyclization of 1,7-enynes. This method provides straightforward access to stable polycyclic products featuring the backbone of the acene series, up to nonacene. ...[more]

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