OER activity manipulated by IrO₆ coordination geometry: an insight from pyrochlore iridates.

ABSTRACT: The anodic reaction of oxygen evolution reaction (OER), an important point for electrolysis, however, remains the obstacle due to its complicated reaction at electrochemical interfaces. Iridium oxide (IrO₂) is the only currently known 5d transition metal oxide possessing admirable OER activity. Tremendous efforts have been carried out to enhance the activity of iridium oxides. Unfortunately there lies a gap in understanding what factors responsible for the activity in doped IrO₂ or the novel crystal structure. Based on two metallic pyrochlores (Bi₂Ir₂O₇ and Pb₂Ir₂O_6.5) and IrO₂. It has been found that there exists a strong correlation between the specific OER activity and IrO₆ coor

SUBMITTER: Sun W 

PROVIDER: S-EPMC5133550 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature