Two cadmium coordination polymers with bridging acetate and phenyl-enedi-amine ligands that exhibit two-dimensional layered structures.

ABSTRACT: Poly[tetra-μ₂-acetato-κ⁸O:O'-bis-(μ₂-benzene-1,2-di-amine-κ²N:N')dicadmium], [Cd₂(CH₃COO)₄(C₆H₈N₂)₂] _n , (I), and poly[[(μ₂-acetato-κ²O:O')(acetato-κ²O,O')(μ₂-benzene-1,3-di-amine-κ²N:N')cadmium] hemihydrate], {[Cd(CH₃COO)₂(C₆H₈N₂)]·0.5H₂O} _n , (II), have two-dimensional polymeric structures in which monomeric units are joined by bridging acetate and benzenedi-amine ligands. Each of the Cd^II ions has an O₄N₂ coordin

SUBMITTER: Geiger DK 

PROVIDER: S-EPMC5137593 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature