Crystal and mol-ecular structures of two silver(I) amidinates, including an unexpected co-crystal with a lithium amidinate.

ABSTRACT: The silver(I) amidinates bis-[μ-N¹,N²-bis-(propan-2-yl)benzamidinato-κ²N¹:N²]disilver(I), [Ag₂(C₁₃H₁₉N₂)₂] or [Ag{PhC(N ⁱ Pr)₂}]₂ (1), and bis-(μ-N¹,N²-di-cyclohexyl-3-cyclo-propyl-propynamidinato-κ²N¹:N²)disilver(I), [Ag₂(C₁₈H₂₇N₂)₂] or [Ag{cyclo-C₃H₅-C≡C-C(NCy)₂}]₂ (2a), exist as centrosymmetric dimers with a planar Ag₂N₄C₂ ring and a common linear coordination of the metal atoms i

SUBMITTER: Wang S 

PROVIDER: S-EPMC5137609 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature