Dataset Information

[N,N-Bis(2-hy-droxy-eth-yl)di-thio-carbamato-κ²S,S']bis-(tri-phenyl-phosphane-κP)copper(I) chloro-form monosolvate: crystal structure, Hirshfeld surface analysis and solution NMR measurements.

ABSTRACT: The title compound, [Cu(C₅H₅NO₂S₂)(C₁₈H₁₅P)₂]·CHCl₃, features a tetra-hedrally coordinated Cu^I atom within a P₂S₂ donor set defined by two phosphane P atoms and by two S atoms derived from a symmetrically coordinating di-thio-carbamate ligand. Both intra- and inter-molecular hy-droxy-O-H⋯O(hydroxy) hydrogen bonding is observed: the former closes an eight-membered {⋯HOC₂NC₂O} ring, whereas the latter connects centrosymmetrically related mol-ecules into dimeric aggregates via eight-membered {⋯H-O⋯H-O}₂ synthons. The complex mol-ecules are arranged to form channels along the c axis in which reside the chloro-form mol-ecules, be

SUBMITTER: Tan SL

PROVIDER: S-EPMC5137612 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

[N,N-Bis(2-hy-droxy-eth-yl)di-thio-carbamato-κ²S,S']bis-(tri-phenyl-phosphane-κP)copper(I) chloro-form monosolvate: crystal structure, Hirshfeld surface analysis and solution NMR measurements.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

[N,N-Bis(2-hy-droxy-eth-yl)di-thio-carbamato-κ2S,S']bis-(tri-phenyl-phosphane-κP)copper(I) chloro-form monosolvate: crystal structure, Hirshfeld surface analysis and solution NMR measurements.

OmicsDI is part of the ELIXIR infrastructure

Tweets

[N,N-Bis(2-hy-droxy-eth-yl)di-thio-carbamato-κ²S,S']bis-(tri-phenyl-phosphane-κP)copper(I) chloro-form monosolvate: crystal structure, Hirshfeld surface analysis and solution NMR measurements.