Synthesis and crystal structure of 4-fluoro-benzyl-ammonium di-hydrogen phosphate, [FC₆H₄CH₂NH₃]H₂PO₄.

ABSTRACT: The asymmetric unit of the title salt, [p-FC₆H₄CH₂NH₃]⁺·H₂PO₄^-, contains one 4-fluoro-benzyl-ammonium cation and one di-hydrogen phosphate anion. In the crystal, the H₂PO₄^- anions are linked by O-H⋯O hydrogen bonds to build corrugated layers extending parallel to the ab plane. The FC₆H₄CH₂NH₃⁺ cations lie between these anionic layers to maximize the electrostatic inter-actions and are linked to the H₂PO₄^- anions through N-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular network. Two hydrogen atoms belonging to the di-hydrogen phosphate anion are statistica

SUBMITTER: Rayes A 

PROVIDER: S-EPMC5137615 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature