Crystal structure of bis-(3,5-di-methyl-pyridine-κN)bis-(methanol-κO)bis-(thio-cyanato-κN)cobalt(II).

ABSTRACT: The asymmetric unit of the title complex, [Co(NCS)₂(C₇H₉N)₂(CH₃OH)₂], comprises of one Co^II cation located on a centre of inversion, one thio-cyanate ligand, one methanol ligand and one 3,5-di-methyl-pyridine ligand. The Co^II cation is octa-hedrally coordinated by two terminal N-bonding thio-cyanate anions, two methanol mol-ecules and two 3,5-di-methyl-pyridine ligands into a discrete complex. The complex mol-ecules are linked by inter-molecular O-H⋯S hydrogen bonding into chains that elongate in the direction parallel to the b axis.

SUBMITTER: Suckert S 

PROVIDER: S-EPMC5137618 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature