Crystal structures of two ansa-titanocene tri-fluoro-methane-sulfonate complexes bearing the Me₂Si(C₅Me₄)₂ ligand.

ABSTRACT: The crystal structures of two ansa-titanocene tri-fluoro-methane-sulfonate complexes bearing the Me₂Si(C₅Me₄)₂ ligand are reported, namely [di-methylbis-(η⁵-tetra-methyl-cyclo-penta-dien-yl)silane](tri-fluoro-methane-sulfonato-κ²O,O')titanium(III) toluene monosolvate, [Ti(CF₃O₃S)(C₂₀H₃₀Si)]·C₇H₈, 1, and chlorido-[di-methyl-bis-(η⁵-tetra-methyl-cyclo-penta-dien-yl)silane](tri-fluoro-methane-sulfonato-κO)titanium(IV), [Ti(CF₃O₃S)(C₂₀H₃₀Si)Cl], 2. Both complexes display a bent metallocene unit, the metal atom being coordinated in a distorted tetra-hedral geometry, wit

SUBMITTER: Kessler M 

PROVIDER: S-EPMC5137621 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature