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Crystal structure of bis-(bis-{μ₃-3-methyl-3-[(4-nitro-2-oxido-benzyl-idene)amino]-propane-1,3-diolato}tris-[chlorido-(dimethyl sulfoxide)-iron(III)]) dimethyl sulfoxide hepta-solvate dihydrate.

ABSTRACT: The title compound, [Fe₃(C₁₁H₁₁N₂O₅)₂Cl₃(C₂H₆OS)₃]₂·7C₂H₆OS·2H₂O, was isolated accidentally from an Fe⁰-NiCl₂·6H₂O-H₃L-TEA-DMSO system [where H₃L is the product of the condensation between p-nitro-salicyl-aldehyde and 2-amino-2-methyl-propane-1,3-diol and dimethyl sulfoxide (DMSO), and TEA is triethylamine]. The structure is based on a trinuclear {Fe₃(μ-O)₄} core, with an angular arrangement of the Fe^III ions that can be explained by the geometrical restrictions of two bulky ligands, each coordinating to all of the metal cations.

SUBMITTER: Chygorin E

PROVIDER: S-EPMC5137625 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(bis-{μ₃-3-methyl-3-[(4-nitro-2-oxido-benzyl-idene)amino]-propane-1,3-diolato}tris-[chlorido-(dimethyl sulfoxide)-iron(III)]) dimethyl sulfoxide hepta-solvate dihydrate.

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Dataset Information

Crystal structure of bis-(bis-{μ3-3-methyl-3-[(4-nitro-2-oxido-benzyl-idene)amino]-propane-1,3-diolato}tris-[chlorido-(dimethyl sulfoxide)-iron(III)]) dimethyl sulfoxide hepta-solvate dihydrate.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structure of bis-(bis-{μ₃-3-methyl-3-[(4-nitro-2-oxido-benzyl-idene)amino]-propane-1,3-diolato}tris-[chlorido-(dimethyl sulfoxide)-iron(III)]) dimethyl sulfoxide hepta-solvate dihydrate.