Imaging molecular geometry with electron momentum spectroscopy.

ABSTRACT: Electron momentum spectroscopy is a unique tool for imaging orbital-specific electron density of molecule in momentum space. However, the molecular geometry information is usually veiled due to the single-centered character of momentum space wavefunction of molecular orbital (MO). Here we demonstrate the retrieval of interatomic distances from the multicenter interference effect revealed in the ratios of electron momentum profiles between two MOs with symmetric and anti-symmetric characters. A very sensitive dependence of the oscillation period on interatomic distance is observed, which is used to determine F-F distance in CF₄ and O-O distance in CO₂ with sub-Ångström precision. Thus, using one spectrometer, and in one measurement, the electron density distributions o

SUBMITTER: Wang E 

PROVIDER: S-EPMC5177885 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature