Crystal structure of catena-poly[[bis-(N-acethyl-thio-morpholine-κS)copper(I)]-μ-iodido].

ABSTRACT: The reaction of copper(I) iodide with N-acetyl-thio-morpholine (L, C₆H₁₁NOS) in aceto-nitrile results in a coordination polymer with composition [CuI(L)₂] _n . The Cu^I atom is coordinated by two S atoms and two I atoms, adopting a distorted tetra-hedral environment. The μ₂-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C-H⋯O hydrogen-bonding inter-actions between the chains lead to a three-dimensional network.

SUBMITTER: Chiang H 

PROVIDER: S-EPMC5209771 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature