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Crystal structure of catena-poly[[bis-(N-acethyl-thio-morpholine-κS)copper(I)]-μ-iodido].

ABSTRACT: The reaction of copper(I) iodide with N-acetyl-thio-morpholine (L, C₆H₁₁NOS) in aceto-nitrile results in a coordination polymer with composition [CuI(L)₂] _n . The Cu^I atom is coordinated by two S atoms and two I atoms, adopting a distorted tetra-hedral environment. The μ₂-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C-H⋯O hydrogen-bonding inter-actions between the chains lead to a three-dimensional network.

SUBMITTER: Chiang H

PROVIDER: S-EPMC5209771 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of catena-poly[[bis-(N-acethyl-thio-morpholine-κS)copper(I)]-μ-iodido].

Chiang Hojae H Kim Tae Ho TH Park Hyunjin H Kim Jineun J

Acta crystallographica. Section E, Crystallographic communications 20170101 Pt 1

The reaction of copper(I) iodide with N-acetyl-thio-morpholine (L, C6H11NOS) in aceto-nitrile results in a coordination polymer with composition [CuI(L)2] n . The CuI atom is coordinated by two S atoms and two I atoms, adopting a distorted tetra-hedral environment. The μ2-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C-H⋯O hydrogen-bonding inter-actions between the chain ...[more]

PMID: 28083135

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