Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol-yne reaction.

ABSTRACT: Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.

SUBMITTER: Lang M 

PROVIDER: S-EPMC5238528 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature