Crystal structures of a novel NNN pincer ligand and its dinuclear titanium(IV) alkoxide pincer complex.

ABSTRACT: This report describes a synthetic protocols and the crystal structures involving a novel pincer-type H₃[NNN] ligand, namely di-μ-bromido-μ-{2-(2,2-di-methylpropanimido-yl)-N-[2-(2,2-di-methyl-propanimido-yl)-4-methyl-phen-yl]-4-methylaniline}-bis-[(diethyl ether)lithium], [Li₂Br₂(C₂₄H₃₃N₃)(C₄H₁₀O)₂] (1) and a dinuclear metal complex, namely di-μ-bromido-2:3κ⁴Br:Br-bis-{2-(2,2-di-methylpropanimido-yl)-N-[2-(2,2-di-methyl-propanimido-yl)-4-methyl-phen-yl]-4-methylaniline}-1κ³N,N',N'';4κ³N,N',N''-tetra-μ-iso-propano-lato-1:2κ⁴O:O;3:4κ⁴O:O

SUBMITTER: Pedziwiatr J 

PROVIDER: S-EPMC5290548 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature