Crystal structure of bis-{(S)-1-[2-(di-phenyl-phosphan-yl)ferrocen-yl]-(R)-eth-yl}ammonium bromide di-chloro-methane monosolvate.

ABSTRACT: During the synthesis of an FeBr₂ complex with the PNP ligand (R,R,S_Fc,S_Fc)-[Fe₂(C₅H₅)₂(C₃₈H₃₅NP₂)] (1), single crystals of the di-chloro-methane monosolvate of the Br^- salt of the protonated ligand 1H⁺ were obtained serendipitously, i.e. [Fe₂(C₅H₅)₂(C₃₈H₃₆NP₂)]Br·CH₂Cl₂. The crystal structure of 1H·Br·CH₂Cl₂ was determined by single-crystal X-ray diffraction. The mean bond lengths in the ferrocene units are Fe-C = 2.049 (3) Å and C-C = 1.422 (4) Å within the cyclo-penta-dienyl rings. Th

SUBMITTER: Zirakzadeh A 

PROVIDER: S-EPMC5290554 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature