Surface Passivation of CdSe Quantum Dots in All Inorganic Amorphous Solid by Forming Cd_1-xZn_xSe Shell.

ABSTRACT: CdSe quantum dots (QDs) doped glasses have been widely investigated for optical filters, LED color converter and other optical emitters. Unlike CdSe QDs in solution, it is difficult to passivate the surface defects of CdSe QDs in glass matrix, which strongly suppress its intrinsic emission. In this study, surface passivation of CdSe quantum dots (QDs) by Cd_1-xZn_xSe shell in silicate glass was reported. An increase in the Se/Cd ratio can lead to the partial passivation of the surface states and appearance of the intrinsic emission of CdSe QDs. Optimizing the heat-treatment condition promotes the incorporation of Zn into CdSe QDs and results in the quenching of the defect emission. Formation of CdSe/Cd_1-xZn_xSe core/graded shell QDs is evidenced by

SUBMITTER: Xia M 

PROVIDER: S-EPMC5294467 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature