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Synthesis of Ordered Mesoporous CuO/CeO₂ Composite Frameworks as Anode Catalysts for Water Oxidation.


ABSTRACT: Cerium-rich metal oxide materials have recently emerged as promising candidates for the photocatalytic oxygen evolution reaction (OER). In this article, we report the synthesis of ordered mesoporous CuO/CeO₂ composite frameworks with different contents of copper(II) oxide and demonstrate their activity for photocatalytic O₂ production via UV-Vis light-driven oxidation of water. Mesoporous CuO/CeO₂ materials have been successfully prepared by a nanocasting route, using mesoporous silica as a rigid template. X-ray diffraction, electron transmission microscopy and N₂ porosimetry characterization of the as-prepared products reveal a mesoporous structure composed of parallel arranged nanorods, with a large surface area and a narrow pore size distribution. The molecular structure and optical pro

SUBMITTER: Markoulaki Ι V 

PROVIDER: S-EPMC5304801 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature