Ultrafast transient IR spectroscopy and DFT calculations of ruthenium(ii) polypyridyl complexes.

ABSTRACT: Ultrafast time-resolved infrared spectroscopy of [Ru(bpy)₃]²⁺ (bpy = 2,2'-bipyridine), [Ru(mbpy)₃]²⁺ (mbpy = 6-methyl-2,2'-bipyridine) and [Ru(mphen)₃]²⁺ (mphen = 2-methyl-1,10'-phenanthroline) in deuterated acetonitrile serves to elucidate the evolution of the system following pulsed excitation into the ¹MLCT band at 400 nm. While for [Ru(bpy)₃]²⁺ no intermediate state can be evidenced for the relaxation of the corresponding ³MLCT state back to the ground state, for [Ru(mbpy)₃]²⁺ and [Ru(mphen)₃]²⁺ an intermediate state with a lifetime of about 400 ps is observed. The species associated IR difference spectra of this state are in good agr

SUBMITTER: Sun Q 

PROVIDER: S-EPMC5308284 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature