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Heterogeneous Nucleation of Trichloroethylene Ozonation Products in the Formation of New Fine Particles.

ABSTRACT: Free radicals in atmosphere have played an important role in the atmospheric chemistry. The chloro-Criegee free radicals are produced easily in the decomposition of primary ozonide (POZ) of the trichloroethylene, and can react with O₂, NO, NO_2, SO₂ and H₂O subsequently. Then the inorganic salts, polar organic nitrogen and organic sulfur compounds, oxygen-containing heterocyclic intermediates and polyhydroxy compounds can be obtained. The heterogeneous nucleation of oxidation intermediates in the formation of fine particles is investigated using molecular dynamics simulation. The detailed nucleation processes are reported. According to molecular dynamics simulation, the nucleation with a diameter of 2 nm is formed in the Organic Compounds-(NH₄)₂SO₄-H₂O system. The spontaneous nucleation is an important process in the formation of fine particles in atmosphere. The model study gives a good example from volatile organic compounds to new fine particles.

SUBMITTER: Wang N

PROVIDER: S-EPMC5309831 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature

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Heterogeneous Nucleation of Trichloroethylene Ozonation Products in the Formation of New Fine Particles.

Wang Ning N Sun Xiaomin X Chen Jianmin J Li Xiang X

Scientific reports 20170215

Free radicals in atmosphere have played an important role in the atmospheric chemistry. The chloro-Criegee free radicals are produced easily in the decomposition of primary ozonide (POZ) of the trichloroethylene, and can react with O2, NO, NO2, SO2 and H2O subsequently. Then the inorganic salts, polar organic nitrogen and organic sulfur compounds, oxygen-containing heterocyclic intermediates and polyhydroxy compounds can be obtained. The heterogeneous ...[more]

PMID: 28198438

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