Understanding surface structure and chemistry of single crystal lanthanum aluminate.

ABSTRACT: The surface crystallography and chemistry of a LaAlO₃ single crystal, a material mainly used as a substrate to deposit technologically important thin films (e.g. for superconducting and magnetic devices), was analysed using surface X-ray diffraction and low energy ion scattering spectroscopy. The surface was determined to be terminated by Al-O species, and was significantly different from the idealised bulk structure. Termination reversal was not observed at higher temperature (600 °C) and chamber pressure of 10^-10 Torr, but rather an increased Al-O occupancy occurred, which was accompanied by a larger outwards relaxation of Al from the bulk positions. Changing the oxygen pressure to 10^-6 Torr enriched the Al site occupancy fraction at the outermost surface

SUBMITTER: Pramana SS 

PROVIDER: S-EPMC5333088 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature