Manipulating charge transfer excited state relaxation and spin crossover in iron coordination complexes with ligand substitution.

ABSTRACT: Developing light-harvesting and photocatalytic molecules made with iron could provide a cost effective, scalable, and environmentally benign path for solar energy conversion. To date these developments have been limited by the sub-picosecond metal-to-ligand charge transfer (MLCT) electronic excited state lifetime of iron based complexes due to spin crossover - the extremely fast intersystem crossing and internal conversion to high spin metal-centered excited states. We revitalize a 30 year old synthetic strategy for extending the MLCT excited state lifetimes of iron complexes by making mixed ligand iron complexes with four cyanide (CN^-) ligands and one 2,2'-bipyridine (bpy) ligand. This enables MLCT excited state and metal-centered excited state energies to be manipulated with p

SUBMITTER: Zhang W 

PROVIDER: S-EPMC5341207 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature