Bis{4-methylbenzyl 2-[4-(propan-2-yl)benzyl-idene]hydrazine-carbodi-thio-ato-κ²N²,S}nickel(II): crystal structure and Hirshfeld surface analysis.

ABSTRACT: The complete mol-ecule of the title hydrazine carbodi-thio-ate complex, [Ni(C₁₉H₂₁N₂S₂)₂], is generated by the application of a centre of inversion. The Ni^II atom is N,S-chelated by two hydrazinecarbodi-thio-ate ligands, which provide a trans-N₂S₂ donor set that defines a distorted square-planar geometry. The conformation of the five-membered chelate ring is an envelope with the Ni^II atom being the flap atom. In the crystal, p-tolyl-C-H⋯π(benzene- ⁱ Pr), ⁱ Pr-C-H⋯π(p-tol-yl) and π-π inter-actions [between p-tolyl rings with inter-centroid distance = 3.8051 (12) Å] help to consolidate the three-dimensional architectu

SUBMITTER: Yusof EN 

PROVIDER: S-EPMC5347063 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature