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Bis(μ₂-N-methyl-N-phenyl-dithio-carbamato)-κ³S,S':S;κ³S:S,S'-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ²S,S')cadmium]: crystal structure and Hirshfeld surface analysis.

ABSTRACT: The title compound, [Cd₂(C₈H₈NS₂)₄], is a centrosymmetric dimer with both chelating and μ₂-tridentate di-thio-carbamate ligands. The resulting S₅ donor set defines a Cd^II coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these inter-actions, along with intra-dimer π-π inter-actions between chelate rings, has been investigated by an analysis of the Hirshfeld surface.

SUBMITTER: Suwardi SA

PROVIDER: S-EPMC5347070 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Bis(μ2-N-methyl-N-phenyl-dithio-carbamato)-κ3S,S':S;κ3S:S,S'-bis-[(N-methyl-N-phenyl-dithio-carbamato-κ2S,S')cadmium]: crystal structure and Hirshfeld surface analysis.

Suwardi Siti Aisyah Nabilah SA Lee See Mun SM Lo Kong Mun KM Jotani Mukesh M MM Tiekink Edward R T ER

Acta crystallographica. Section E, Crystallographic communications 20170221 Pt 3

The title compound, [Cd2(C8H8NS2)4], is a centrosymmetric dimer with both chelating and μ2-tridentate di-thio-carbamate ligands. The resulting S5 donor set defines a CdII coordination geometry inter-mediate between square-pyramidal and trigonal-bipyramidal, but tending towards the former. The packing features C-H⋯S and C-H⋯π inter-actions, which generate a three-dimensional network. The influence of these int ...[more]

PMID: 28316825

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