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Crystal structure of (2,2'-bi-pyridine-κ²N,N')bis-(3,5-di-tert-butyl-o-benzo-quinonato-κ²O,O')ruthenium(II).

ABSTRACT: In the title mononuclear complex, [Ru(C₁₄H₂₀O₂)₂(C₁₀H₈N₂)], the Ru^II ion has a distorted octa-hedral coordination environment defined by two N atoms of the chelating 2,2'-bi-pyridine ligand and four O atoms from two 3,5-di-tert-butyl-o-benzo-quinone ligands. In the crystal, the complex mol-ecules are linked by inter-molecular C-H⋯O hydrogen bonds and π-π stacking inter-actions between the 2,2'-bi-pyridine ligands [centroid-centroid distance = 3.538 (3) Å], resulting in a layer structure extending parallel to the ab plane.

SUBMITTER: Faizi MS

PROVIDER: S-EPMC5347077 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of (2,2'-bi-pyridine-κ2N,N')bis-(3,5-di-tert-butyl-o-benzo-quinonato-κ2O,O')ruthenium(II).

Faizi Md Serajul Haque MS Ali Akram A Potaskalov Vadim A VA

Acta crystallographica. Section E, Crystallographic communications 20170228 Pt 3

In the title mononuclear complex, [Ru(C14H20O2)2(C10H8N2)], the RuII ion has a distorted octa-hedral coordination environment defined by two N atoms of the chelating 2,2'-bi-pyridine ligand and four O atoms from two 3,5-di-tert-butyl-o-benzo-quinone ligands. In the crystal, the complex mol-ecules are linked by inter-molecular C-H⋯O hydrogen bonds and π-π stacking inter-actions between the 2,2'-b ...[more]

PMID: 28316832

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