The chemistry of ZnWO₄ nanoparticle formation.

ABSTRACT: The need for a change away from classical nucleation and growth models for the description of nanoparticle formation is highlighted. By the use of in situ total X-ray scattering experiments the transformation of an aqueous polyoxometalate precursor mixture to crystalline ZnWO₄ nanoparticles under hydrothermal conditions was followed. The precursor solution is shown to consist of specific Tourné-type sandwich complexes. The formation of pristine ZnWO₄ within seconds is understood on the basis of local restructuring and three-dimensional reordering preceding the emergence of long range order in ZnWO₄ nanoparticles. An observed temperature dependent trend in defect concentration can be rationalized based on the proposed formation mechanism. Following nu

SUBMITTER: Bojesen ED 

PROVIDER: S-EPMC5355961 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature