Unknown

Dataset Information

0

Manganese-Catalyzed Carboacylations of Alkenes with Alkyl Iodides.

ABSTRACT: A manganese-catalyzed carboacylation of alkenes with alkyl iodides and carbon monoxide is described. This carbonylative difunctionalization uses both primary and secondary alkyl iodides in reactions with a diverse array of cyclic and acyclic substrates. Examples of successful applications to the synthesis of five-, six-, and seven-membered rings are provided. The inexpensive, first-row catalytic system and mild reaction conditions are expected to facilitate applications in complex synthesis.

SUBMITTER: McMahon CM 

PROVIDER: S-EPMC5359471 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Manganese-Catalyzed Carboacylations of Alkenes with Alkyl Iodides.

McMahon Caitlin M CM   Renn Matthew S MS   Alexanian Erik J EJ  

Organic letters 20160809 16

A manganese-catalyzed carboacylation of alkenes with alkyl iodides and carbon monoxide is described. This carbonylative difunctionalization uses both primary and secondary alkyl iodides in reactions with a diverse array of cyclic and acyclic substrates. Examples of successful applications to the synthesis of five-, six-, and seven-membered rings are provided. The inexpensive, first-row catalytic system and mild reaction conditions are expected to facilitate applications in complex synthesis. ...[more]

Similar Datasets

Unknown Nickel-Catalyzed Carbonylative Synthesis of Functionalized Alkyl Iodides.
| S-EPMC6197950 | biostudies-literature
Unknown Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides.
| S-EPMC5531607 | biostudies-literature
Unknown Hydroboration of Terminal Alkenes and trans-1,2-Diboration of Terminal Alkynes Catalyzed by a Manganese(I) Alkyl Complex.
| S-EPMC8596825 | biostudies-literature
Unknown Manganese-Catalyzed Stereospecific Hydroxymethylation of Alkyl Tosylates.
| S-EPMC7147876 | biostudies-literature
Unknown Palladium-Catalyzed Carbocyclizations of Unactivated Alkyl Bromides with Alkenes Involving Auto-tandem Catalysis.
| S-EPMC5632513 | biostudies-literature
Unknown Iron-Catalyzed Reductive Coupling of Alkyl Iodides with Alkynes To Yield cis-Olefins: Mechanistic Insights from Computation.
| S-EPMC6990637 | biostudies-literature
Unknown Fe-catalyzed three-component dicarbofunctionalization of unactivated alkenes with alkyl halides and Grignard reagents.
| S-EPMC8163237 | biostudies-literature
Unknown Palladium-catalyzed difluoromethylthiolation of heteroaryl bromides, iodides, triflates and aryl iodides.
| S-EPMC6008600 | biostudies-literature
Unknown Metal-Free Radical Borylation of Alkyl and Aryl Iodides.
| S-EPMC6470957 | biostudies-literature
Unknown Palladium-Catalyzed Fluorosulfonylvinylation of Organic Iodides.
| S-EPMC5653204 | biostudies-literature