Radicals and molecular products from the gas-phase pyrolysis of lignin model compounds. Cinnamyl alcohol.

ABSTRACT: The experimental results on detection and identification of intermediate radicals and molecular products from gas-phase pyrolysis of cinnamyl alcohol (CnA), the simplest non-phenolic lignin model compound, over the temperature range of 400-800 °C are reported. The low temperature matrix isolation - electron paramagnetic resonance (LTMI-EPR) experiments along with the theoretical calculations, provided evidences on the generation of the intermediate carbon and oxygen centered as well as oxygen-linked, conjugated radicals. A mechanistic analysis is performed based on density functional theory to explain formation of the major products from CnA pyrolysis; cinnamaldehyde, indene, styrene, benzaldehyde, 1-propynyl benzene, and 2-propenyl benzene. The evaluated bond dissociation patterns and uni

SUBMITTER: Khachatryan L 

PROVIDER: S-EPMC5363761 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature