Remarkably enhanced photovoltaic effects and first-principles calculations in neodymium doped BiFeO₃.

ABSTRACT: Remarkably enhanced photovoltaic effects have been observed in the heterostructures of p-type A-site Nd³⁺-doped BiFeO₃ (Bi_0.9375Nd_0.0625)FeO₃ (or BFONd) polycrystalline ceramics and the n-type ITO thin film. The maximum power conversion is ~0.82%, which is larger than 0.015% in BiFeO₃ (BFO) under blue-ultraviolet irradiation of wavelength λ = 405 nm. The current-voltage (I-V) characteristic curve suggests a p-n junction interface between the ITO thin film and BFO (or BFONd) ceramics. The band gaps calculated from first-principles for BFO and BFONd are respectively 2.25 eV and 2.23 eV, which are consistent with the experimental direct band gaps of 2.24 eV and 2.20 eV measured by optical transmission spectra. The reduction of

SUBMITTER: Peng YT 

PROVIDER: S-EPMC5364538 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature