Thermochromic Luminescent Materials and Multi-Emission Bands in d¹⁰ Clusters.

ABSTRACT: Thermochromic luminescent compounds with d¹⁰ metal ions are interesting materials for applications such as sensors or display devices. However, these properties are difficult to predict prior to their synthesis. In this communication, we investigated materials with structural assemblies known to be responsible of distinct luminescence mechanisms and show that they can be interesting potential thermometers. Thus, we compared the synthesis of a zinc halide and a copper halide based compounds which only differ in their ability to create clusters with metallophilic interactions. The compounds synthesized by hydrothermal method have been structurally characterized by Single-crystal X-ray diffraction, Solid-State NMR, FTIR, UV-Visible spectroscopy, thermal analysis and EPR. The photol

SUBMITTER: Gautier R 

PROVIDER: S-EPMC5371983 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature