Unravelling the mechanisms of vibrational relaxation in solution.

ABSTRACT: We present a systematic study of the mode-specific vibrational relaxation of NO₂ in six weakly-interacting solvents (perfluorohexane, perfluoromethylcyclohexane, perfluorodecalin, carbon tetrachloride, chloroform, and d-chloroform), chosen to elucidate the dominant energy transfer mechanisms in the solution phase. Broadband transient vibrational absorption spectroscopy has allowed us to extract quantum state-resolved relaxation dynamics of the two distinct NO₂ fragments produced from the 340 nm photolysis of N₂O₄ → NO₂(X) + NO₂(A) and their separate paths to thermal equilibrium. Distinct relaxation pathways are observed for the NO₂ bending and stretching modes, even at energies as high as 7000 cm^-1 abov

SUBMITTER: Grubb MP 

PROVIDER: S-EPMC5380915 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature