Crystal structure of bis-(1,10-phenanthroline-κ²N,N')(1,3-thia-zole-2-thiol-ato-κ²S²,N)nickel(II) hexa-fluorido-phosphate 1,4-dioxane sesquisolvate.

ABSTRACT: The title salt, [Ni(C₃H₂NS₂)(C₁₂H₈N₂)₂]PF₆·1.5C₄H₈O₂, was the unexpected product on making an attempt to prepare an [Ni(2-mercapto-thia-zol-ate)(1,10-phenanthroline)]⁺ complex by reaction of [NiCl₂(1,10-phen-an-throline)] with 2-mercapto-thia-zolate. In the resulting complex, the 2-mercapto-thia-zolate anion acts as a chelating ligand, which coordinates to the Ni^II ion with the thia-zolyl N and thiol-ate S atoms. In the crystal, π-π stacking inter-actions between the coordinating 1,10-phenanthroline mol-ecules of adjacent complexes result in a zigzag chain running parallel to the c axis. Weak C-H⋯X (X = O, F) hydrogen

SUBMITTER: Kai K 

PROVIDER: S-EPMC5382628 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature