Sculpting Silica Colloids by Etching Particles with Nonuniform Compositions.

ABSTRACT: We present the synthesis of new shapes of colloidal silica particles by manipulating their chemical composition and subsequent etching. Segments of silica rods, prepared by the ammonia catalyzed hydrolysis and condensation of tetraethylorthosilicate (TEOS) from polyvinylpyrrolidone loaded water droplets, were grown under different conditions. Upon decreasing temperature, delaying ethanol addition, or increasing monomer concentration, the rate of dissolution of the silica segment subsequently formed decreased. A watery solution of NaOH (∼mM) selectively etched these segments. Further tuning the conditions resulted in rod-cone or cone-cone shapes. Deliberately modulating the composition along the particle's length by delayed addition of (3-aminopropyl)-triethoxysilane (APTES) also allowed us

SUBMITTER: Hagemans F 

PROVIDER: S-EPMC5390506 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature