Dataset Information

Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO₂ Hydrogenation: Integrated Reaction and Catalyst Separation for CO₂ -Scrubbing Solutions.

ABSTRACT: Aqueous biphasic systems were investigated for the production of formate-amine adducts by metal-catalyzed CO₂ hydrogenation, including typical scrubbing solutions as feedstocks. Different hydrophobic organic solvents and ionic liquids could be employed as the stationary phase for cis-[Ru(dppm)₂ Cl₂ ] (dppm=bis-diphenylphosphinomethane) as prototypical catalyst without any modification or tagging of the complex. The amines were found to partition between the two phases depending on their structure, whereas the formate-amine adducts were nearly quantitatively extracted into the aqueous phase, providing a favorable phase behavior for the envisaged integrated reaction/separation sequence. The solvent pair of methyl isobutyl carbinol (MIBC) and water led to the

SUBMITTER: Scott M

PROVIDER: S-EPMC5396146 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Dataset Information

Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO₂ Hydrogenation: Integrated Reaction and Catalyst Separation for CO₂ -Scrubbing Solutions.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Dataset Information

Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO2 Hydrogenation: Integrated Reaction and Catalyst Separation for CO2 -Scrubbing Solutions.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Aqueous Biphasic Systems for the Synthesis of Formates by Catalytic CO₂ Hydrogenation: Integrated Reaction and Catalyst Separation for CO₂ -Scrubbing Solutions.