μ₃-Chlorido-μ₂-chlorido-(μ₃-pyrrolidine-1-carbo-dithio-ato-κ⁴S:S,S':S')tris-[(tri-ethyl-phosphane-κP)copper(I)]: crystal structure and Hirshfeld surface analysis.

ABSTRACT: The title trinuclear compound, [Cu₃(C₅H₈NS₂)Cl₂(C₆H₁₅P)₃], has the di-thio-carbamate ligand symmetrically chelating one Cu^I atom and each of the S atoms bridging to another Cu^I atom. Both chloride ligands are bridging, one being μ₃- and the other μ₂-bridging. Each Et₃P ligand occupies a terminal position. Two of the Cu^I atoms exist within Cl₂PS donor sets and the third is based on a ClPS₂ donor set, with each coordination geometry based on a distorted tetra-hedron. The constituents defining the core of the mol-ecule, i.e. Cu₃Cl₂S₂, occupy seven corners of a distorted cube. In t

SUBMITTER: Tan YJ 

PROVIDER: S-EPMC5418792 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature