POMzites: A Family of Zeolitic Polyoxometalate Frameworks from a Minimal Building Block Library.

ABSTRACT: We describe why the cyclic heteropolyanion [P₈W₄₈O₁₈₄]^40- (abbreviated as {P₈W₄₈}) is an ideal building block for the construction of intrinsically porous framework materials by classifying and analyzing >30 coordination polymers incorporating this polyoxometalate (POM) ligand. This analysis shows that the exocyclic coordination of first-row transition metals (TMs) to {P₈W₄₈} typically yields frameworks which extend through {W-O-TM-O-W} bridges in one, two, or three dimensions. However, despite the rich structural diversity of such compounds, the coordination of TMs to the {P₈W₄₈} ring is poorly understood, and therefore largely unpredictable, and had not until now been present wit

SUBMITTER: Boyd T 

PROVIDER: S-EPMC5423706 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature