Amine-Functionalized Covalent Organic Framework for Efficient SO₂ Capture with High Reversibility.

ABSTRACT: Removing sulfur dioxide (SO₂) from exhaust flue gases of fossil fuel power plants is an important issue given the toxicity of SO₂ and subsequent environmental problems. To address this issue, we successfully developed a new series of imide-linked covalent organic frameworks (COFs) that have high mesoporosity with large surface areas to support gas flowing through channels; furthermore, we incorporated 4-[(dimethylamino)methyl]aniline (DMMA) as the modulator to the imide-linked COF. We observed that the functionalized COFs serving as SO₂ adsorbents exhibit outstanding molar SO₂ sorption capacity, i.e., PI-COF-m10 record 6.30 mmol SO₂ g^-1 (40 wt%). To our knowledge, it is firstly reported COF as SO₂ sorbent to date.

SUBMITTER: Lee GY 

PROVIDER: S-EPMC5429627 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature