Carbodiphosphorane mediated synthesis of a triflyloxyphosphonium dication and its reactivity towards nucleophiles.

ABSTRACT: A carbodiphosphorane ((Ph₃P)₂C) mediated synthesis of the first triflyloxyphosphonium dication (12+) bearing two electrophilic sites is presented. Depending on the nucleophile, 12+ reacts selectively either at the sulfur atom of the triflyloxy moiety or at the directly attached phosphorus atom. In substitution reactions at the phosphorus atom the triflyloxy moiety serves as a leaving group and enables the synthesis of rare examples of pseudo-halophosphonium dications.

SUBMITTER: Yogendra S 

PROVIDER: S-EPMC5433424 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature