Efficient hydrogen production on MoNi₄ electrocatalysts with fast water dissociation kinetics.

ABSTRACT: Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report a MoNi₄ electrocatalyst supported by MoO₂ cuboids on nickel foam (MoNi₄/MoO₂@Ni), which is constructed by controlling the outward diffusion of nickel atoms on annealing precursor NiMoO₄ cuboids on nickel foam. Experimental and theoretical results confirm that a rapid Tafel-step-decided hydrogen evolution proceeds on MoNi₄ electrocatalyst. As a result, the MoNi₄ electrocatalyst exhibits zero onset overpotential

SUBMITTER: Zhang J 

PROVIDER: S-EPMC5442356 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature