1,6- and 1,7-Regioisomers of Highly Soluble Amino-Substituted Perylene Tetracarboxylic Dianhydrides: Synthesis, Optical and Electrochemical Properties.

ABSTRACT: 1,6- and 1,7-regioisomers of diamino-substituted perylene tetracarboxylic dianhydrides (PTCDs) with different n-alkyl chain lengths (n = 6, 12 or 18) were synthesized and characterized by NMR spectroscopy and high-resolution mass spectrometry. These dyes are highly soluble in most organic solvents and even in nonpolar solvents, such as hexane. To the best of our knowledge, this is the first time the 1,6-diamino-substituted PTCDs (2a-2c) have been obtained in pure form. The regioisomers 1a-1c (1,7-) and 2a-2c (1,6-) exhibit significant differences in their optical characteristics. In addition to the longest wavelength absorption band at around 674 nm, 2a-2c exhibit another shoulder band at ca. 600 nm, and consequently, co

SUBMITTER: Chen KY 

PROVIDER: S-EPMC5455523 | biostudies-literature | 2015 Aug

REPOSITORIES: biostudies-literature