A New Homogeneous Catalyst for the Dehydrogenation of Dimethylamine Borane Starting with Ruthenium(III) Acetylacetonate

ABSTRACT: The catalytic activity of ruthenium(III) acetylacetonate was investigated for the first time in the dehydrogenation of dimethylamine borane. During catalytic reaction, a new ruthenium(II) species is formed in situ from the reduction of ruthenium(III) and characterized using UV-Visible, Fourier transform infrared (FTIR), 1H NMR, and mass spectroscopy. The most likely structure suggested for the ruthenium(II) species is mer-[Ru(N2Me4)3(acac)H]. Mercury poisoning experiment indicates that the catalytic dehydrogenation of dimethylamine-borane is homogeneous catalysis. The kinetics of the catalytic dehydrogenation of dimethylamine borane starting with Ru(acac)3 were studied depending on the catalyst concentration, substrate concentration and temperature. The hydrogen generation was found to be

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PROVIDER: S-EPMC5455753 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature