Singlet Exciton Fraction in Electroluminescence from Conjugated Polymer.

ABSTRACT: The efficiency of electrofluorescent polymer light-emitting diodes is determined by singlet exciton fraction (χ_S) formation and its value still remains controversial. In this work, χ_S in spiropolyfluorene (SPF) is determined by analyzing transient emission of phosphor-dopant probe. The χ_S is found to range from 50% to 76%, depending on applied voltage. Higher applied voltage gives larger χ_S. Besides, more rapid increment in χ_S with applied voltage is observed in the higher-molecular-weight polymer. The voltage or molecular weight dependence of χ_S suggests the probability of singlet exciton (SE) generation through triplet-triplet annihilation (TTA) is enhanced due to higher triplet exciton (TE) concentration at higher applied

SUBMITTER: Jen TH 

PROVIDER: S-EPMC5460123 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature