(BEDT-TTF)₂Cu₂(HCOO)₅: An Organic-Inorganic Hybrid Conducting Magnet.

ABSTRACT: A dual-functional organic-inorganic hybrid (BEDT-TTF)₂Cu₂(HCOO)₅ (1) (BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene) was obtained through the electrochemical oxidation of neutral BEDT-TTF in the presence of an ammonium salt of the one-dimensional copper-formate framework [(C₂H₅)₃NH]₂Cu₂(HCOO)₅ in a C₆H₅Cl-C₂H₅OH solution. Compound 1 was composed of organic donor BEDT-TTF⁺⁰⋅⁵ in a θ-phase arrangement and Jahn-Teller distorted (4,4) grid anion sheets [Cu₂(HCOO)₅^-] _n with S=1/2. We identified the material as a semiconductor with values of σ_300K

SUBMITTER: Zhang B 

PROVIDER: S-EPMC5474655 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature