Imaging metal-like monoclinic phase stabilized by surface coordination effect in vanadium dioxide nanobeam.

ABSTRACT: In correlated systems, intermediate states usually appear transiently across phase transitions even at the femtosecond scale. It therefore remains an open question how to determine these intermediate states-a critical issue for understanding the origin of their correlated behaviour. Here we report a surface coordination route to successfully stabilize and directly image an intermediate state in the metal-insulator transition of vanadium dioxide. As a prototype metal-insulator transition material, we capture an unusual metal-like monoclinic phase at room temperature that has long been predicted. Coordinate bonding of L-ascorbic acid molecules with vanadium dioxide nanobeams induces charge-carrier density reorganization and stabilizes metallic monoclinic vanadium dioxide, unravelling orbital

SUBMITTER: Li Z 

PROVIDER: S-EPMC5474733 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature