Insight into the Electrical Double Layer of an Ionic Liquid on Graphene.

ABSTRACT: Graphene is a promising next-generation conducting material with the potential to replace traditional electrode materials in supercapacitors. Since energy storage in supercapacitors relies on the electrolyte-electrode interface, here we elucidate the interfacial subnanometer structure of a single component liquid composed solely of cations and anions - an ionic liquid- on electrified graphene. We study the effect of applied potential on the interaction between graphene and a silicon tip in an ionic liquid and describe it within the framework of the Derjaguin-Landau-Verwey-Overbeck (DLVO) theory. The energy is stored in an electrical double layer composed of an extended Stern layer, which consists of multiple ion layers over ~2 nanometers, beyond which a diffuse layer forms to compensate th

SUBMITTER: Jurado LA 

PROVIDER: S-EPMC5484676 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature