Unknown

Dataset Information

0

Nitrite reduction by copper through ligand-mediated proton and electron transfer.

ABSTRACT: Nitrite reduction by a copper complex featuring a proton-responsive tripodal ligand is demonstrated. Gaseous nitric oxide was confirmed as the sole NO X by-product in quantitative yield. DFT calculations predict that nitrite reduction occurs via a proton and electron transfer process mediated by the ligand. The reported mechanism parallels nitrite reduction by copper nitrite reductase.

SUBMITTER: Moore CM 

PROVIDER: S-EPMC5490426 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Nitrite reduction by copper through ligand-mediated proton and electron transfer.

Moore Cameron M CM   Szymczak Nathaniel K NK  

Chemical science 20150414 6

Nitrite reduction by a copper complex featuring a proton-responsive tripodal ligand is demonstrated. Gaseous nitric oxide was confirmed as the sole NO <sub><i>X</i></sub> by-product in quantitative yield. DFT calculations predict that nitrite reduction occurs <i>via</i> a proton and electron transfer process mediated by the ligand. The reported mechanism parallels nitrite reduction by copper nitrite reductase. ...[more]

Similar Datasets

Unknown Demonstration of proton-coupled electron transfer in the copper-containing nitrite reductases.
| S-EPMC2757998 | biostudies-literature
Unknown SmI2(H2O)n Reduction of Electron Rich Enamines by Proton-Coupled Electron Transfer.
| S-EPMC5812026 | biostudies-literature
Unknown Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release.
| S-EPMC6896986 | biostudies-literature
Unknown Spectroscopic and computational studies of nitrite reductase: proton induced electron transfer and backbonding contributions to reactivity.
| S-EPMC2629382 | biostudies-literature
Unknown Electron and Proton Flux for Carbon Dioxide Reduction in Methanosarcina barkeri During Direct Interspecies Electron Transfer.
| S-EPMC6315138 | biostudies-literature
Unknown Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct.
| S-EPMC3874213 | biostudies-literature
Unknown Terminal Electron-Proton Transfer Dynamics in the Quinone Reduction of Respiratory Complex I.
| S-EPMC6300313 | biostudies-literature
Unknown Separating Proton and Electron Transfer Effects in Three-Component Concerted Proton-Coupled Electron Transfer Reactions.
| S-EPMC5812448 | biostudies-literature
Unknown Consecutive Ligand-Based Electron Transfer in New Molecular Copper-Based Water Oxidation Catalysts.
| S-EPMC8456863 | biostudies-literature
Unknown Mechanistic Dichotomy in Proton-Coupled Electron-Transfer Reactions of Phenols with a Copper Superoxide Complex.
| S-EPMC6584633 | biostudies-literature